Quantitative analysis of cross-talk in partly deuterated samples of nuclear spins hyperpolarized by dynamic nuclear polarization (DNP) in the thermal mixing regime

Autor: Bogdan A. Rodin, Vineeth Thalakottoor, Mathieu Baudin, Nicolas Birilirakis, Geoffrey Bodenhausen, Alexandra V. Yurkovskaya, Daniel Abergel
Rok vydání: 2023
Předmět:
Zdroj: Physical Chemistry Chemical Physics. 25:15040-15051
ISSN: 1463-9084
1463-9076
DOI: 10.1039/d3cp00453h
Popis: DNP cross-talk experiments in the thermal mixing regime provide energy transfer rates between the different reservoirs. The dependence of the kinetic parameters on the radical concentration and H/D ratio sheds light onto the nature of “hidden” spins.
Databáze: OpenAIRE