Excited state interactions of thiopyrylium salts

Autor:	Kiyoshi Inomata, Sylvie Parret, Takeo Matsumoto, F. Morlet-Savary, J. P. Fouassier
Rok vydání:	1998
Předmět:	chemistry.chemical_compound Photopolymer Monomer chemistry Absorption spectroscopy Excited state Physical and Theoretical Chemistry Nanosecond laser Thiopyrylium Photochemistry Dissociation (chemistry)
Zdroj:	Journal of the Chemical Society, Faraday Transactions. 94:745-752
ISSN:	1364-5455 0956-5000
DOI:	10.1039/a707307k
Popis:	The photophysics and photochemistry of thiopyrylium salts have been investigated by UV–VIS absorption spectroscopy and nanosecond laser absorption spectroscopy. The effect of substituents of the heterocycle on the photophysical properties was analysed. Dissociation of peroxidic compounds photosensitized by these salts was studied. The interaction with monomers and many other additives has also been investigated. A mechanism is proposed for the initiation of acrylic photopolymerization reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::add396a09b2fa1df164304f20fcec5c8 https://doi.org/10.1039/a707307k Zobrazit plný text záznamu