Using the Marcus Inverted Region for Rectification in Donor−Bridge−Acceptor 'Wire' Assemblies

Autor:	Carol Creutz, Bruce S. Brunschwig, N. Sutin
Rok vydání:	2003
Předmět:	Materials science Rectification Field (physics) Materials Chemistry Nanotechnology Metal electrodes Physical and Theoretical Chemistry Acceptor Bridge (interpersonal) Molecular physics Surfaces Coatings and Films Voltage
Zdroj:	The Journal of Physical Chemistry B. 107:10687-10690
ISSN:	1520-5207 1520-6106
DOI:	10.1021/jp035542s
Popis:	We examine the properties of a system in which a hopping mechanism can exploit the nuclear factors, along with the field resulting from the applied voltage, to control the current through a donor−bridge−acceptor (D−B−A) system inserted between two metal electrodes. We find that, by utilizing D/A couples with small λ values, switching can be achieved at modest applied potentials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::adad507a37804dd5a1acc6371c0d347d https://doi.org/10.1021/jp035542s Zobrazit plný text záznamu