ChemInform Abstract: Selective Bromochlorination of endo-1,4-Dibromotricyclo(5.2.1.02,6) deca-3,8-diene-5,10-dione 10-Ethylene Acetal at the Conjugated Carbon- Carbon Double Bond
Autor: | J. Tsanaktsidis, K. J. Parker, R. W. Gable |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 25 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199436081 |
Popis: | Exposure of (1) to bromine in thionyl chloride/ dimethylformamide produced (5), the result of regio- and stereo-selective addition of bromine chloride across the carbonyl-conjugated double bond. The structure of (5) was determined by X-ray crystallography, and its mode of formation is discussed in terms of the carbonyl attack mechanism. |
Databáze: | OpenAIRE |
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