ChemInform Abstract: Selective Bromochlorination of endo-1,4-Dibromotricyclo(5.2.1.02,6) deca-3,8-diene-5,10-dione 10-Ethylene Acetal at the Conjugated Carbon- Carbon Double Bond

Autor: J. Tsanaktsidis, K. J. Parker, R. W. Gable
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 25
ISSN: 0931-7597
DOI: 10.1002/chin.199436081
Popis: Exposure of (1) to bromine in thionyl chloride/ dimethylformamide produced (5), the result of regio- and stereo-selective addition of bromine chloride across the carbonyl-conjugated double bond. The structure of (5) was determined by X-ray crystallography, and its mode of formation is discussed in terms of the carbonyl attack mechanism.
Databáze: OpenAIRE