Phosphorescent heteroleptic iridium(III) cyclometallates: Improved syntheses of acetylacetonate complexes and quantum chemical studies of their excited state properties
| Autor: | Victor G. Young, Robert D. Sanner, Nerine J. Cherepy, Hung Q. Pham |
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| Rok vydání: | 2020 |
| Předmět: |
Denticity
010405 organic chemistry Chemistry Acetylacetone chemistry.chemical_element 010402 general chemistry 01 natural sciences Acceptor 0104 chemical sciences Inorganic Chemistry Crystallography chemistry.chemical_compound Excited state Octahedral molecular geometry Materials Chemistry Iridium Physical and Theoretical Chemistry Triplet state Phosphorescence |
| Zdroj: | Polyhedron. 176:114256 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2019.114256 |
| Popis: | We have investigated methods to prepare cyclometallated iridium(III) complexes with efficient photoluminescence spanning a broad color palette. In particular, we find that addition of ancillary ligands to chloro-bridged iridium dimers proceeds cleanly in refluxing 1,2-dimethoxyethane (DME) without the need for additional product purification. This represents an improvement over the conventional use of 2-ethoxyethanol which requires column chromatographic separation. Our efforts in this work have focused on acetylacetonate complexes such as (F2ppy)2Ir(acac), where F2ppy = 2-(4′,6′-diflurophenyl)pyridinato. We have prepared fifteen compounds by the route, eight of which are newly reported; in four cases we were able to prepare complexes which were inaccessible via the conventional route. Nine of the complexes were characterized by single crystal x-ray diffraction and possess the same distorted octahedral geometry around the iridium with two bidentate phenylpyridine ligands and one bidentate acetylacetonate ligand. Seven of the complexes exhibited efficient photoluminescence with colors ranging from yellow to blue and quantum yields of 0.51–0.74. All of the compounds with trifluoromethyl or phenyl substituents on the acetylacetone displayed emission in the orange with low quantum efficiency. The use of TD-DFT calculations, along with natural transition orbitals (NTOs), permitted a detailed interpretation of the electronic structures for the complexes. The nature of the acceptor orbitals for the low energy triplet state NTOs proved to be an important predictor for the emission spectra of the compounds. |
| Databáze: | OpenAIRE |
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