Structural Level Characterization of Base Oils Using Advanced Analytical Techniques
| Autor: | Frédérick Adam, S. Mani Sarathy, Adnan Al-Hajji, Saroj K. Panda, Hendrik Muller, Nadim Hourani, Matthias Witt |
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| Rok vydání: | 2015 |
| Předmět: |
Chromatography
Atmospheric pressure General Chemical Engineering Analytical technique Base oil Analytical chemistry Energy Engineering and Power Technology Atmospheric-pressure chemical ionization High-performance liquid chromatography Fourier transform ion cyclotron resonance chemistry.chemical_compound Fuel Technology chemistry Petroleum Gas chromatography |
| Zdroj: | Energy & Fuels. 29:2962-2970 |
| ISSN: | 1520-5029 0887-0624 |
| DOI: | 10.1021/acs.energyfuels.5b00038 |
| Popis: | Base oils, blended for finished lubricant formulations, are classified by the American Petroleum Institute into five groups, viz., groups I–V. Groups I–III consist of petroleum based hydrocarbons whereas groups IV and V are made of synthetic polymers. In the present study, five base oil samples belonging to groups I and III were extensively characterized using high performance liquid chromatography (HPLC), comprehensive two-dimensional gas chromatography (GC×GC), and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) equipped with atmospheric pressure chemical ionization (APCI) and atmospheric pressure photoionization (APPI) sources. First, the capabilities and limitations of each analytical technique were evaluated, and then the availed information was combined to reveal compositional details on the base oil samples studied. HPLC showed the overwhelming presence of saturated over aromatic compounds in all five base oils. A similar trend was further corroborated using GC×GC, which yie... |
| Databáze: | OpenAIRE |
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