Intercalation from the liquid phase of n-alkylamines (n = 1–6) and cyclic amines in α-hafnium phosphate

Autor: Julio Rodríguez, Marta Suárez, M. Luz Rodríguez, Ricardo Llavona, Ana Vega, L. M. Barcina
Rok vydání: 1997
Předmět:
Zdroj: Journal of the Chemical Society, Dalton Transactions. :2757
ISSN: 1364-5447
0300-9246
Popis: The intercalation behaviour from the liquid phase of n-alkylamines (n = 1–6) and the cyclic amines aniline, benzylamine, cyclohexylamine, piperidine and pyridine in α-hafnium phosphate Hf(HPO 4 ) 2 ·H 2 O has been studied. The composition of the intercalation compounds was determined and the arrangement of the amines in the interlayer region as mono-(pyridine) or bi-molecular films (the remaining amines) is discussed from data obtained from X-ray diffraction, IR spectroscopy and chemical and thermal analysis.
Databáze: OpenAIRE