ChemInform Abstract: Stereoselective Cyanohydrin Forming Reactions of Chiral α-Amino Aldehydes

Autor:	Manfred T. Reetz, Mark Wilhelm Drewes, Klaus Harms, W. Reif
Rok vydání:	1988
Předmět:	chemistry.chemical_compound Stereochemistry Chemistry Diastereomer Stereoselectivity Chelation General Medicine Lewis acids and bases Optically active Cyanohydrin Adduct
Zdroj:	ChemInform. 19
ISSN:	0931-7597
DOI:	10.1002/chin.198850126
Popis:	The Lewis acid mediated cyanohydrin-forming addition of Me3SiCN to optically active α-dibenzylamino aldehydes 2 occurs stereoselectively. Chelation controlled adducts 3 result if MgBr2 or TiCl4 is used, whereas the diastereomers 4 are obtained upon employing BF3, ZnBr2 or SnCl4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ad7f653051fb37d02e11fce8b5adca9c https://doi.org/10.1002/chin.198850126 Zobrazit plný text záznamu Plný text