Elucidating the structural redox behaviors of nanostructured expanded graphite anodes toward fast-charging and high-performance lithium-ion batteries
| Autor: | Dong-Kyu Son, Jisu Kim, Michael Ruby Raj, Gibaek Lee |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Intercalation (chemistry) chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Microstructure 01 natural sciences Exfoliation joint 0104 chemical sciences Chemical engineering chemistry General Materials Science Lithium Graphite Crystallite 0210 nano-technology Faraday efficiency Shrinkage |
| Zdroj: | Carbon. 175:187-201 |
| ISSN: | 0008-6223 |
| DOI: | 10.1016/j.carbon.2021.01.015 |
| Popis: | In this study, the systematic thermal exfoliation of expandable graphite was investigated to determine the optimum temperature for high volume of expansion and to enlarge the interlayer spacing distance (d-spacing) of expanded graphite (EG). The structural redox behaviors of nanostructured EGs as high-rate anodes for Li-ion storage were thoroughly investigated using various analyses, including an analysis of the electrochemical Li-ion de/intercalation kinetics (structure-dependent Li-ion transport properties) in lithium-ion batteries (LIBs). According to SEM and XRD analyses, all the EG samples exhibit a worm-like morphology containing honeycomb-like micro-pores, and highly crystalline structure with a shrinkage in the d-spacing. Interestingly, EG that is heat-treated for 30 min (EG30) exhibits the largest shrinkage with a d-spacing of 3.37 A and a crystallite size of 20.96 nm at the optimal thermal exfoliation temperature of 600 °C while retaining analogous long-range-ordered graphitic layers/sheets. Moreover, EG30 exhibited excellent performance in LIBs, with an extremely high average reversible specific capacity of ∼338 mAh g−1 at a current density of 100 mA g−1, a high rate capability of ∼112 mAh g−1 even at an ultra-high rate of 3 A g−1, and a Coulombic efficiency of approximately 100%. The results obtained herein demonstrate that subtle changes in the thermal exfoliation time significantly affect both the honeycomb-like microstructure and Li-ion reversible de/intercalation kinetics of the EG samples, which leading to entirely different staged phase transitions. The shrinkage in the d-spacing of EG as well as crystallite orientation by thermal exfoliation provide new insights for the design and development of EG, which can be exploited to produce competitive EGs for LIBs that power electric vehicles (EVs) and portable electronic devices. |
| Databáze: | OpenAIRE |
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