Chemical speciation and bioavailability of lead and cadmium in an aquatic system polluted by sewage discharges

Autor: Rajkamal Sarin, Vaidyanathan N. Iyer
Rok vydání: 1992
Předmět:
Zdroj: Chemical Speciation & Bioavailability. 4:135-142
ISSN: 2047-6523
0954-2299
DOI: 10.1080/09542299.1992.11083192
Popis: A physico-chemical scheme encompassing anodic stripping voltammetry (ASV) as an analytical tool, and ultraviolet irradiation techniques, has been applied to determine the species of lead and cadmium in sewage polluted and unpolluted fresh-waters of a major perennial river located downstream of a metropolitan city in India. The physico-chemical and bioavailable species that have been identified and quantified include ASV-labile (bioavailable), particulate bound, total dissolved, non-labile or bound and organically bound metal. For precise and rapid assessment of the toxic bioavailable fraction, the ASV technique has been proposed as an analytical tool.The river stretch, divided into reference, impact and recovery zones, has been monitored for any alteration in the distribution and partitioning of Pb and Cd amongst various physico-chemical forms. An attempt has been made to assess the impact of effluent discharge upon the receiving river by correlating concentrations of various metal-species with re...
Databáze: OpenAIRE