The kinetics of the reaction between cyclopentene and aqueous hydrogen peroxide under phase-transfer catalysis
| Autor: | Yu. A. Moskvichev, A. E. Meshechkina, G. V. Rybina, S. S. Srednev, A. S. Shevchuk, L. V. Mel’nik |
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| Rok vydání: | 2015 |
| Předmět: |
Aqueous solution
General Chemical Engineering Inorganic chemistry Kinetics Energy Engineering and Power Technology Epoxide General Chemistry Photochemistry Catalysis Reaction rate chemistry.chemical_compound Fuel Technology chemistry Geochemistry and Petrology Phase (matter) Cyclopentene Hydrogen peroxide |
| Zdroj: | Petroleum Chemistry. 55:51-56 |
| ISSN: | 1555-6239 0965-5441 |
| Popis: | The kinetics of the reaction between cyclopentene and an aqueous solution of hydrogen peroxide under phase-transfer catalysis conditions has been studied. The activation energies of the successive stages of cyclopentene epoxidation to 1,2-epoxycyclopentane and the hydration of the resulting epoxide to 1,2-cyclopentanediol have been found, and the orders of the reactions with respect to the reactants have been determined. A mathematical model of the process that adequately describes the available experimental data in the entire range of reactant concentrations has been proposed. |
| Databáze: | OpenAIRE |
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