Hydrogenation of oleic acid to 9-octadecen-1-ol with rhenium-tin catalyst
| Autor: | Shuichi Niwa, Yuen-May Choo, Kien-Yoo Cheah, Makoto Toba, Fujio Mizukami, Thin-Sue Tang |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
inorganic chemicals
organic chemicals General Chemical Engineering Catalyst support Organic Chemistry chemistry.chemical_element Ammonium perrhenate Rhenium equipment and supplies Heterogeneous catalysis Catalyst poisoning Catalysis Oleic acid chemistry.chemical_compound chemistry Organic chemistry heterocyclic compounds Tin |
| Zdroj: | Journal of the American Oil Chemists' Society. 70:601-605 |
| ISSN: | 0003-021X |
| DOI: | 10.1007/bf02545327 |
| Popis: | A new supported bimetallic catalyst, rhenium-tin, is able to reduce oleic acid to 9-octadecen-1-ol (cis andtrans isomers) with appreciable yield under mild hydrogenation conditions. This paper reports investigations on the effects of catalyst preparation methods, types of support, catalyst raw materials, mole ratio of the metals, activation and reaction conditions on the activity and selectivity of the catalyst. Catalyst derived from the combination of ammonium perrhenate and stannic chloride on alumina gave the best performance, and the presence of tin in the catalyst is essential for the preservation of the olefinic bond of the oleic acid during hydrogenation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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