Reactivity of Ph3PNLi towards PIII and PV electrophiles

Autor:	Marie Agnès Lacour, Marc Taillefer, Jean-Noël Volle, Nicolas J. Rahier
Rok vydání:	2008
Předmět:	General method 010405 organic chemistry Phosphorus Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences 3. Good health chemistry Computational chemistry Drug Discovery Electrophile Organic chemistry Reactivity (chemistry)
Zdroj:	Tetrahedron. 64:6645-6650
ISSN:	0040-4020
Popis:	A study of the reactivity of Ph3P NLi towards phosphorus electrophiles allowed us to develop a general method to isolate, or cleanly generate in situ, a broad family of polyphosphinimines displaying P N–P bonds. A preliminary application of this methodology is presented here with the synthesis of various Schwesinger-type bases by a simple new procedure employing Ph3P NLi.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ad34b7af125eb2f9a4673e34c2a6887d https://doi.org/10.1016/j.tet.2008.05.019 Zobrazit plný text záznamu Full Text from ScienceDirect