Synthesis and crystal structure of aquachlorobis(1,10-phenanthroline)manganese(II) nitrobenzoate trihydrate

Autor:	Tu-Gen Xu, Duan-Jun Xu
Rok vydání:	2005
Předmět:	Hydrogen bond Phenanthroline Inorganic chemistry Stacking chemistry.chemical_element Crystal structure Manganese Crystallography chemistry.chemical_compound Molecular geometry chemistry Octahedral molecular geometry Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Coordination Chemistry. 58:437-442
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958970412331335719
Popis:	The title compound has been prepared and its crystal structure determined by X-ray diffraction methods. The complex salt consists of Mn(II) complex cations, benzoate anions and lattice water molecules. Mn(II) assumes a distorted octahedral geometry defined by two 1,10-phenanthroline (phen) ligands, a Cl− ion and a water molecule. A comparison of bond distances and bond angles suggests electrostatic interaction between Mn(II) and coordinated N atoms. The nitrobenzoate anion does not coordinate to the Mn atom but links with the complex cation via O−H···O hydrogen bonds. Aromatic stacking occurs between phen rings and between phen and benzoate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ad330c90a03c7665554b239cc044c875 https://doi.org/10.1080/00958970412331335719 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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