Synthesis and characterization of a magnetically recoverable molybdenum(VI) nanocatalyst for eco-friendly oxidation of alcohols
| Autor: | Z. Pakdin Parizi, M. Tavakoli Hafshejani, Samira Saeednia, M. Hatefi Ardakani |
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| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
Schiff base 010405 organic chemistry Inorganic chemistry Metals and Alloys chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Furfuryl alcohol Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Benzyl alcohol Molybdenum Alcohol oxidation Materials Chemistry Magnetic nanoparticles Selectivity Nuclear chemistry |
| Zdroj: | Transition Metal Chemistry. 41:767-774 |
| ISSN: | 1572-901X 0340-4285 |
| DOI: | 10.1007/s11243-016-0077-9 |
| Popis: | A catalyst based on immobilization of a molybdenum(VI) Schiff base complex on γ-Fe2O3 magnetic nanoparticles has been synthesized and characterized. This catalyst was employed for the selective oxidation of alcohols to the corresponding carbonyl compounds in EtOH/H2O2. The catalyst can be easily separated from the reaction mixture by decantation using an external magnet and reused efficiently in five subsequent reaction cycles without any significant decrease in activity or selectivity. |
| Databáze: | OpenAIRE |
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