Cobalt-catalyzed photopromoted carbonylation of chloroalkanes in the presence of KI

Autor:	Jing Mei Yin, Shen Min Li, Ying Ping Jia, Ying Na Cui, Da Bin Gao, Guang Yun Zhou, Xiangsheng Wang
Rok vydání:	2010
Předmět:	chemistry.chemical_element General Chemistry Medicinal chemistry Chloride Catalysis Ion chemistry.chemical_compound Iodide ion chemistry medicine Cobalt compounds Organic chemistry Cobalt Carbonylation Carbon monoxide medicine.drug
Zdroj:	Chinese Chemical Letters. 21:1033-1036
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2010.04.027
Popis:	The photopromoted carbonylation of chloroalkanes with carbon monoxide catalyzed by cobalt compounds [Co(OAc)2, CoCl2] in the presence of KI was carried out under ambient conditions. The results revealed that the catalytic activity of Co(OAc)2 was higher than that of CoCl2. A basic additive NaOAc was beneficial to the reaction. Interestingly, with NaOAc as an additive, Co(OAc)2 and CoCl2 exhibited similar catalytic activity. Preliminary work showed that the role of iodide ion was initially to form active iodoalkanes via substituting chloride ion in chloroalkanes in situ, and then, the carbonylation of iodoalkanes proceeded under irradiation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ad2418f2da35869907c97cb3e2e4825a https://doi.org/10.1016/j.cclet.2010.04.027 Zobrazit plný text záznamu Full Text from ScienceDirect