Oxygenation studies. Part 9. Mechanistic studies on the oxygenation of cyclooctene at [{RhCl(C8H14)2}2]

Autor:	Vladimir Šik, Janet Shaw, Patrick W. Fowler, Gordon Read
Rok vydání:	1991
Předmět:	Allylic rearrangement Reaction mechanism Ligand chemistry.chemical_element General Chemistry Carbon-13 NMR Photochemistry Medicinal chemistry Rhodium chemistry.chemical_compound chemistry Cyclooctene Benzene Isomerization
Zdroj:	J. Chem. Soc., Dalton Trans.. :1087-1092
ISSN:	1364-5447 0300-9246
Popis:	The complex [{RhCl(C8H14)2}2] in benzene containing cis-[5-2H1]-cyclooctene has been shown to undergo ligand exchange at 26°C at a very much faster rate than oxygenative breakdown. Double-bond isomerisation competes with the latter. The principal oxygenated product is a mixture of monodeuterioisotopomers of cyclooctanone which has been shown, by 13C NMR analysis, to have been formed by oxygenative attack on the vinylic carbons rather than on the allylic centres or on π-allylic intermediates. The findings are related to earlier mechanistic proposals for oxygenation of alkenes catalysed by rhodium species.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ad1a3c513c161872a072d70dab25d574 https://doi.org/10.1039/dt9910001087 Zobrazit plný text záznamu