Acetonitrile: far-infrared spectra and chemical thermodynamic properties. Discussion of an entropy discrepancy

Autor:	Bobby R. Cook, Gene A. Crowder
Rok vydání:	1967
Předmět:	chemistry.chemical_compound chemistry Far infrared Bending vibration Inorganic chemistry General Engineering Thermodynamics Infrared spectroscopy Physics::Chemical Physics Physical and Theoretical Chemistry Acetonitrile Spectral line
Zdroj:	The Journal of Physical Chemistry. 71:914-916
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100863a022
Popis:	Liquid- and vapor-state infrared spectra in the region 75-650 cm/sup -1/ were obtained for acetonitrile. The entropy discrepancy at 298.15/sup 0/K was shown to result partially from the use of the liquid-state frequency for the skeletal bending vibration. The remaining entropy discrepancy is discussed. A table of the chemical thermodynamic properties of acetonitrile at selected temperatures was prepared.
Databáze:	OpenAIRE
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