Excited-state dynamics of trans,trans-distyrylbenzene: A femtosecond transient absorption study

Autor:	Hsu Feng-Cheng, Sheng Hsien Lin, Juen-Kai Wang
Rok vydání:	2005
Předmět:	education.field_of_study Photoisomerization Chemistry Population Analytical chemistry General Physics and Astronomy Molecular physics Spectral line Excited state Femtosecond Ultrafast laser spectroscopy Transient (oscillation) Physical and Theoretical Chemistry education Spectroscopy
Zdroj:	Chemical Physics Letters. 411:103-107
ISSN:	0009-2614
Popis:	We report a study of excited-state dynamics of trans,trans-distyrylbenzene in hexane solution with femtosecond two-color transient absorption spectroscopy. Excited-state spectra at different pump–probe time delays were extracted and exhibit a spectral shift in 10 ps. This 10-ps transient behavior is proposed to reflect an energy transfer process to a new intermediate state and the transferred population then relaxes through emitting photons. Its implications for photoisomerization and the comparison with trans-stilbene are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::acf5de9f3e38dad07db25217c1ccf0ca https://doi.org/10.1016/j.cplett.2005.06.036 Zobrazit plný text záznamu Full Text from ScienceDirect