Refractory-Metal Diffusion Inhibitors Slow Erosion of Catalytic Metal Particles in the growth of Carbon Nanotubes
| Autor: | Melissa King, Michael J. Bronikowski |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
Nanostructure Materials science Diffusion chemistry.chemical_element 02 engineering and technology Carbon nanotube 010402 general chemistry 01 natural sciences Catalysis law.invention law General Materials Science organic chemicals Mechanical Engineering Refractory metals 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences chemistry Chemical engineering Mechanics of Materials Molybdenum Erosion Particle 0210 nano-technology |
| Zdroj: | MRS Advances. 4:197-204 |
| ISSN: | 2059-8521 |
| Popis: | Catalytic growth of substantial amounts of Carbon Nanotubes (CNTs) to lengths greater than 1 – 2 cm is currently limited by several factors, including especially the deactivation of the catalyst particles due to erosion of catalyst atoms from the catalyst particles at elevated CNT growth temperatures. Inclusion of refractory metals in the CNT growth catalyst has recently been proposed as a method to prevent this catalytic particle erosion and deactivation, allowing the CNT to grow for greater times and reach substantially greater lengths. Here are presented results of recent investigations into this method. The system investigated employs Molybdenum as the erosion inhibitor and Iron as the CNT growth catalyst. Results show that inclusion of Mo leads to substantially longer catalyst particle lifetimes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink