Reactions photochimiques et thermiques de quelques cobaloximes en presence de composes soufres

Autor: G. Merle, C. Giannoti
Rok vydání: 1976
Předmět:
Zdroj: Journal of Organometallic Chemistry. 113:45-56
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)91759-5
Popis: In this paper we report the photoinduced and thermal insertion of sulfur in the CoC bond of some alkyl- and aryl-cobaloximes, the most important products being organic or organometallic tetrasulfides. We also report the photosubstitution of one tetrasulfide and two organic disulfides on the alkylcobaloximes, giving compounds of the type RS n R and RS n (Co)Py with η = 14.
Databáze: OpenAIRE