Acetyl ketene aminals in Nenitzescu reaction

Autor:	E. K. Panisheva, Alexander V. Komkov, L. M. Alekseeva, Vladimir G Granik, O. S. Anisimova, T. I. Mukhanova, V. A. Dorokhov, K. F. Turchin
Rok vydání:	1999
Předmět:	chemistry.chemical_compound chemistry Ketene Organic chemistry General Chemistry Benzoquinone
Zdroj:	Russian Chemical Bulletin. 48:160-165
ISSN:	1573-9171 1066-5285
Popis:	Nenitzescu reaction of acetyl ketene aminals (N,N-acetals) was investigated. The interaction of 2-acetyl-1-amino-1-anilinoethene with benzoquinone gave 3-acetyl-2-amino-7a-hydroxy-1-phenyl-5,7a-dihydro-1H-indol-5-one, which was then transformed into 3-acetyl-2-amino-6-chloro-5-hydroxy-1-phenylindole. The reaction of benzoquinone with 2-acetyl-1-amino-1-benzoylaminoethene led to the corresponding hydroquinone-adduct which was oxidized to 4-acetylamino-5-(2,5-dihydroxyphenyl)-2-phenyloxazole.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ac93e30e0ed808afd8a264e55b0e7f30 https://doi.org/10.1007/bf02494420 Zobrazit plný text záznamu Full text from SpringerLink