Palladium(II) Acetate Catalyzed Cyclization–Coupling of (o-Ethynylphenyl)phosphonic Acid Monoesters with Allyl Halides

Autor: Zecai Xiao, Ai-Yun Peng
Rok vydání: 2019
Předmět:
Zdroj: Synthesis. 51:3499-3505
ISSN: 1437-210X
0039-7881
DOI: 10.1055/s-0039-1689936
Popis: A Pd(OAc)2-catalyzed tandem cyclization–coupling reaction of (o-ethynylphenyl)phosphonic acid monoesters and allyl halides has been developed. This reaction provides an efficient, mild, general and regioselective way to synthesize 4-allylphosphaisocoumarins.
Databáze: OpenAIRE