Stereodynamics of the reactions of () with C2H4 and C2H6

Autor:	Okitsugu Kajimoto, Hiroshi Tsurumaki, Yo Fujimura
Rok vydání:	1999
Předmět:	Angular momentum Crystallography Oxygen atom Structural change Computational chemistry Chemistry General Physics and Astronomy Physical and Theoretical Chemistry Polarization (electrochemistry) Spectroscopy Tautomer Plane of rotation
Zdroj:	Chemical Physics Letters. 301:145-152
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(98)01459-6
Popis:	Stereodynamics of the reactions of O ( 1 D ) with C2H4 and C2H6 have been observed with Doppler-resolved polarization spectroscopy. The differential cross-sections suggest that each reaction proceeds via an insertion pathway involving an alcohol-type intermediate complex. The angular momentum polarization indicated a primary contribution of the H–O–C bending motion of the complexes to the product rotation for both reactions. For the C2H4 reaction, the spatial correlation between the incident direction of the oxygen atom and the OH plane of rotation is lost because of the structural change of the complex accompanied by keto–enol tautomerization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ac6abc17dfa145b4cdd2f6073f0b5a55 https://doi.org/10.1016/s0009-2614(98)01459-6 Zobrazit plný text záznamu Full Text from ScienceDirect