Oxidative Polymerization of 2,6-Dimethylphenol by Copper(II)Chloride-Amine Complexes: Effect of Amines on Polymerization Activity

Autor:	Swaminathan Sivaram, Nakayu N. Chavan, Bhaskar B. Idage, Bhimrao D. Sarawade, Sudhakar S. Mahajan
Rok vydání:	1991
Předmět:	chemistry.chemical_compound Living free-radical polymerization Anionic addition polymerization Polymerization Chemistry Radical polymerization Polymer chemistry General Engineering Cationic polymerization Copper(II) chloride Solution polymerization Ionic polymerization
Zdroj:	Journal of Macromolecular Science: Part A - Chemistry. 28:7-13
ISSN:	0022-233X
Popis:	2, 6-Dimethylphenol (2, 6-DMP) undergoes oxidative polymerization with CuCl2.2H2O-aliphatic amine complexes in a 70:30(v/v) o-dichlorobenzene-ethanol solvent. Unlike pyridine, polymerization occurs even in the absence of added base. Apart from basicity, factors such as steric effects and nature of ligand coordination to Cu(II) have profound effect on catalyst reactivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ac41e4a4a115f9ec5c85ab0e272c9e22 https://doi.org/10.1080/00222339108054377 Zobrazit plný text záznamu