| Popis: |
Multiplicity features of autocatalytic reactions in isothermal catalyst particles with diffusion interaction are presented. Discussed also are two types of autocatalytic reactions—A + B → 2B (quadratic) and A + 2B → 3B (cubic)—and a decay reaction for autocatalyst B, B → C, and a nonautocatalytic reaction, A → B, which generates the autocatalyst. For quadratic reactions, the bifurcation diagrams for a catalyst particle are similar to those for a CSTR. The location of the branch solution, however, is somewhat different. For cubic autocatalytic reactions, the exact parameter regions, where the isola, mushroom, reverse-S, and reverse-S-plus-isola patterns of bifurcation exist, are determined. Furthermore, the parameter space, where a unique solution exists for all Thiele moduli, is also given. |
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