ChemInform Abstract: (2,2,8,8-Tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis(dicarbonyl-(methylcyclopentadienyl)manganese), the First Complexed Bis(phosphavinyl)ether

Autor: Bernhard Powietzka, Basil Kanellakopulos, Rainer Balles, Gerd Becker, Helmut Schmidt, Bernd Nuber, Manfred L. Ziegler
Rok vydání: 1987
Předmět:
Zdroj: ChemInform. 18
ISSN: 0931-7597
DOI: 10.1002/chin.198749285
Popis: The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units (abbreviated here as Mn).
Databáze: OpenAIRE