ChemInform Abstract: (2,2,8,8-Tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis(dicarbonyl-(methylcyclopentadienyl)manganese), the First Complexed Bis(phosphavinyl)ether
Autor: | Bernhard Powietzka, Basil Kanellakopulos, Rainer Balles, Gerd Becker, Helmut Schmidt, Bernd Nuber, Manfred L. Ziegler |
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Rok vydání: | 1987 |
Předmět: | |
Zdroj: | ChemInform. 18 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.198749285 |
Popis: | The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units (abbreviated here as Mn). |
Databáze: | OpenAIRE |
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