Aromatic Polyhedral Hydroxyborates: Bridging Boron Oxides and Boron Hydrides

Autor:	M. Frederick Hawthorne, Toralf Peymann, Carolyn B. Knobler, Axel Herzog
Rok vydání:	1999
Předmět:	Hydroxylation chemistry.chemical_compound chemistry Icosahedral symmetry Inorganic chemistry Polymer chemistry chemistry.chemical_element General Chemistry Boron Hydrides Boron Hydrogen peroxide Catalysis
Zdroj:	Angewandte Chemie International Edition. 38:1061-1064
ISSN:	1521-3773 1433-7851
Popis:	No explosion, but per-B-hydroxylation occurs if the icosahedral boron hydrides [closo-B12 H12 ](2-) (see picture), [closo-CB11 H12 ](-) , or closo-1,12-(CH2 OH)2 -1,12-C2 B10 H10 are refluxed in 30 % hydrogen peroxide. Thus, the three isoelectronic species [closo-B12 (OH)12 ](2-) , [closo-1-H-1-CB11 (OH)11 ](-) , and closo-1,12-H2 -1,12-C2 B10 (OH)10 were obtained. ○=BH, ○=BOH.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ac210ad7f318638879dbdca58e9798d5 https://doi.org/10.1002/(sici)1521-3773(19990419)38:8<1061::aid-anie1061>3.0.co Zobrazit plný text záznamu Plný text