Stereoretentive introduction of (E)- and (Z)-γ-alkoxyallyl groups into carbonyl compounds via light-promoted reaction with γ-alkoxyallylstannanes

Autor: Akio Takuwa, Hidetoshi Iwamoto, Seiji Ebara, Yutaka Nishigaichi
Rok vydání: 1998
Předmět:
Zdroj: Chemical Communications. :1789-1790
ISSN: 1364-548X
1359-7345
DOI: 10.1039/a804459g
Popis: The light-promoted condensation between carbonyl compounds and (E)- or (Z)-γ-alkoxyallylstannanes affords predominantly the linear homoallylic alcohols, with retention of the double bond geometry of the γ-alkoxyallyl moieties.
Databáze: OpenAIRE