Synthesis and characterization of TiO2 and palm oil fiber ash hybrid photocatalysts for seawater pretreatment

Autor: Abdulkarim Abdulrahman Mohamed Suliman, Abdul Latif Ahmad, Ruzinah Isha, Mazrul Nizam Abu Seman
Rok vydání: 2020
Předmět:
Zdroj: Maejo International Journal of Energy and Environmental Communication. 2:11-20
ISSN: 2774-0064
2673-0537
DOI: 10.54279/mijeec.v2i3.245035
Popis: Titanium dioxide (TiO2) has been used in various applications such as air purification, water purification, and photoelectrochemical conversion systems. However, developing advanced materials with enhanced performance for catalytic applications, especially water treatment, is highly required. This work aims to study the effect of (TiO2) photocatalyst in pretreatment seawater desalination. The catalyst with a mass ratio of TiO2: palm oil fibre ash (POFA) at 0:100, 40:60, 60:40, and 100:0 was synthesized via wet impregnation. The catalyst was calcined at 500 ℃ for four hours. The mixture of artificial seawater and catalyst at a mass ratio of photocatalyst: artificial seawater at 1:300 was put in a one-litre borosilicate photo-reactor fixed with mercury light of 350 nm for two hours with stirring at 1000 rpm. In this investigation, an evaporator was used to collect the freshwater. The fresh and spent catalysts were characterized via X-Ray Diffractogram (XRD), Nitrogen physisorption analysis, Diffuse Reflectance Spectrometer (DRS), Scanning Electron Microscopy (SEM), and Energy Dispersive X-Ray Spectroscopy (EDX). The catalyst with Ti: palm oil fibre ash (POFA) at 40:60 and 60:40 can reduce the COD at 45 % and 41%, respectively. As more OPFA was added into the hybrid TiO2 catalyst, there has been a change in the properties of seawater due to the use of special evaporators, especially EC and TDS. It can be deduced that the hybrid TiO2 photocatalyst synthesized with OPFA has vast potential to treat seawater.
Databáze: OpenAIRE