The Mechanisms of Polystyrene Destruction Under Influence of Powerful UV-Radiation: Initial Stages

Autor: G. A. Matyushin, K. M. Dyumayev, V. V. Lobko, A. V. Chadov, N. P. Kuzmina, V. S. Nechitailo
Rok vydání: 1992
Předmět:
Zdroj: International Journal of Polymeric Materials and Polymeric Biomaterials. 17:121-130
ISSN: 1563-535X
0091-4037
DOI: 10.1080/00914039208041107
Popis: Physical processes stipulating photoinitiation of polystyrene destruction under influence of powerful UV-radiation treatment are considered. The experimental results on its photolysis at UV-irradiation in different spectral ranges are given confirming the decisive role of triplet-triplet transfer of excitation energy from benzene rings to simple bonds, and triplet-triplet annihilation on the initial stages of photodestruction.
Databáze: OpenAIRE