The role of excited states in the photolysis of n-butyraldehyde, II. Intersystem crossing quantum yields

Autor:	A. Nacsa, M. Tölgyesi, Tibor Bérces
Rok vydání:	1977
Předmět:	chemistry.chemical_compound Intersystem crossing Chemistry Excited state Singlet fission Quantum yield Singlet state Physical and Theoretical Chemistry Piperylene Photochemistry Butyraldehyde Isomerization Catalysis
Zdroj:	Reaction Kinetics and Catalysis Letters. 7:45-51
ISSN:	1588-2837 0133-1736
DOI:	10.1007/bf02068551
Popis:	Singlet → triplet intersystem crossing quantum yields were determined for n-butyraldehyde, using the photosensitized cis-trans isomerization of piperylene to monitor the process. At room temperature and 313 nm, 0.58±0.05 and 0.72±0.05 were obtained for the triplet yield in the vapor phase and in isooctane, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::abedb938660ff891f8e509b79455ded7 https://doi.org/10.1007/bf02068551 Zobrazit plný text záznamu Full text from SpringerLink