Ferric perchlorate-mediated radical reactions of [60]fullerene

Autor:	Wang GuanWu, LI FaBao
Rok vydání:	2012
Předmět:	Fullerene derivatives chemistry.chemical_compound Reaction mechanism Malonate Fullerene Chemistry Organic chemistry Surface modification General Chemistry Ferric perchlorate
Zdroj:	Science China Chemistry. 55:2009-2017
ISSN:	1869-1870 1674-7291
DOI:	10.1007/s11426-012-4714-7
Popis:	Transition-metal-salt-mediated radical reactions of fullerenes have attracted extensive attention as a new and important method for fullerene functionalization. The application of relatively cheap and easily available ferric perchlorate (Fe(ClO4)3) to the synthesis of [60]fullerene (C60) has demonstrated remarkable advantages and afforded a series of novel fullerene derivatives. In this review we present our recent progress in this area and summarize the reactions of C60 with malonate esters, β-keto esters, nitriles, aldehydes/ketones, and arylboronic acids in the presence of Fe(ClO4)3 to afford the C60-fused disubstituted lactones, C60-fused hemiketal, C60-fused dihydrofuran, C60-fused oxazoles, C60-fused 1,3-dioxolanes, and fullerenyl boronic esters. The possible reaction mechanisms for the above-mentioned reactions are also described in detail.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::abe036729aed8721ee4ea5caa5af2b8f https://doi.org/10.1007/s11426-012-4714-7 Zobrazit plný text záznamu Full text from SpringerLink