Glycosylations of Tertiary Alcohols: Synthesis of Fully Protected Disaccharides with Sterically Demanding Groups Attached to the Sugar Core
| Autor: | Jordi Bertran Vicente, Annika Holkenbrink, Daniel B. Werz |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
Steric effects
chemistry.chemical_classification animal structures Glycosylation Stereochemistry Organic Chemistry Disaccharide Glycoside Core (manufacturing) macromolecular substances Catalysis carbohydrates (lipids) chemistry.chemical_compound chemistry lipids (amino acids peptides and proteins) Glycosyl Sugar Tertiary alcohols |
| Zdroj: | Synthesis. 2009:2596-2604 |
| ISSN: | 1437-210X 0039-7881 |
| Popis: | Modified gluco- and galactopyranosides with sterically demanding groups in the 4-position were synthesized. Glycosylation studies of these tertiary alcohols with glycosyl trichloroacetimidates and glycosyl phosphates were performed. Despite steric hindrance the modified disaccharide moieties could be assembled in moderate yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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