Synthesis of Methyl Aziridine-2-Chloro-2-Carboxyletes through Electroreductive Cross Coupling of Methyl Trichloroacetate with Aromatic Imines

Autor:	Pravin S. Kendrekar, Hirofumi Maekawa, Ikuzo Nishiguchi
Rok vydání:	2007
Předmět:	Coupling (electronics) chemistry.chemical_compound chemistry Supporting electrolyte Electrode Imine Polymer chemistry Methyl trichloroacetate Stereoselectivity Aziridine
Zdroj:	ECS Transactions. 6:1-7
ISSN:	1938-6737 1938-5862
DOI:	10.1149/1.2790394
Popis:	Electroreductive of aromatic imine derivatives (1) with methyl trichloroacetate (2) in N,N-dimethylacetamide (DMAc) containing Et4NBr as a supporting electrolyte using an undivided cell equipped with Zn-plates as the electrodes under constant current conditions brought about stereoselective cross coupling to give the corresponding methyl aziridine 2- carboxylates (3) in good to moderate yields.
Databáze:	OpenAIRE
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