Supercritical-Carbon-Dioxide Solubility Characteristics of Polyphenols and Polyphenol Derivatives

Autor:	Hiro Yamamoto, Hiroshi Shiraishi, Toshio Sakamizu
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Supercritical carbon dioxide Polymers and Plastics Chemistry Hydrogen bond Polyphenol Carboxylic acid Organic Chemistry Materials Chemistry food and beverages Organic chemistry Solubility Dissolution
Zdroj:	Journal of Photopolymer Science and Technology. 19:367-372
ISSN:	1349-6336 0914-9244
DOI:	10.2494/photopolymer.19.367
Popis:	Supercritical carbon dioxide (scCO2) solubility characteristics of various polyphenols and their derivatives were investigated for the sake of resist materials for scCO2 development. Some 3 nuclei-polyphenols were fairly soluble in scCO2 at the condition of pressure: 15MPa, temperature: 38 °C. Among various subustituent groups, only carboxylic acid COOH structure was a strong dissolution-inhibition factor, but other polar groups, hydroxyl, carboxylic-acid ester structures, such as methyl, ethyl, ter-butyl esters, were not fatal dissolution-inhibition factors in the films for scCO2. It was presumed that existence of hydrogen bonding interaction in the film strongly affect the film dissolution in scCO2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::abacf9f4f443eb1d3057d71b4b5e6a55 https://doi.org/10.2494/photopolymer.19.367 Zobrazit plný text záznamu