Reaction of 1-bromo-3-chloropropane with tellur and dimethyltelluride in the system of hydrazine hydrate-alkali

Autor:	Ekaterina P. Levanova, D. S. Totyashinova, E. R. Zhanchipova, E. N. Sukhomazova, V. A. Grabel’nykh, I. M. Korotaeva, A. V. Elaev, N. V. Russavskaya, Lyudmila V. Klyba, A. I. Albanov, N. A. Korchevin
Rok vydání:	2006
Předmět:	Hydrazine chemistry.chemical_element General Chemistry Alkylation Alkali metal chemistry.chemical_compound chemistry Propane Polymer chemistry Mass spectrum Organic chemistry Hydrate Tellurium Methyl iodide
Zdroj:	Russian Journal of General Chemistry. 76:726-729
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363206050112
Popis:	A synthesis of oligomeric substance of thiocol type, the poly(trimethyleneditelluride), from 1-bromo-3-chloropropane and elemental tellurium is performed using a hydrazine hydrate-alkali system. Reductive splitting of the tellurocol followed by alkylation with methyl iodide give rise to preparation of bis(methyltelluro)propane, which was synthesized also from dimethyltelluride and 1,3-dihalopropanes using the N2H4·H2O/KOH system. Mass spectra of the synthesized low molecular weight organotellurium compounds are considered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aba274da8ff3857b3c3986eb6a79fe83 https://doi.org/10.1134/s1070363206050112 Zobrazit plný text záznamu Plný text ve formátu PDF