Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions
| Autor: | Ilya A. Khodov, Victor V. Borovkov, Dmitriy A. Lazovskiy, Olga V. Maltceva, Oscar I. Koifman, Nugzar Zh. Mamardashvili, Galina M. Mamardashvili |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
biology
Chemistry Hydrogen bond Ligand Supramolecular chemistry Stacking 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics biology.organism_classification 01 natural sciences Fluorescence Porphyrin Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Viscosity chemistry.chemical_compound Polymer chemistry Materials Chemistry Tetra Physical and Theoretical Chemistry 0210 nano-technology Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 277:1047-1053 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2018.12.118 |
| Popis: | Supramolecular triads consisting of hydrophilic Sn(IV)-tetra(4-sulfophenyl)-porphyrin and two axial guests such as propylphenol, tyrosine, and 2-(2-hydroxyphenyl)-benzoxazole were synthesized. The structures of synthesized complexes were identified by experimental spectroscopic and quantum-chemical simulation methods, and their fluorescent properties were studied in various viscosity media (mixed phosphate buffer-glycerin solvents of different composition). The effect of axial ligand structure on the fluorescent properties of these triads (due to the hydrogen bonding or π-π stacking between the components of «host-guest» systems) is discussed. The potential use of synthesized complexes as environmental probes of local viscosity is proposed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect