Synthesis and structure of the palladium complexes [Ph3P(CH2)3PPh3][PdBr4], [Ph3P(CH2)3PPh3][Pd2Br6]·DMF, and [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2

Autor:	V. S. Senchurin, Olga K. Sharutina, I. A. Il’chenko, P. V. Andreev, Vladimir V. Sharutin
Rok vydání:	2017
Předmět:	chemistry.chemical_compound Chemistry Dimethyl sulfoxide Inorganic chemistry chemistry.chemical_element Recrystallization (metallurgy) General Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Palladium
Zdroj:	Russian Journal of General Chemistry. 87:122-127
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363217010194
Popis:	Complexes [Ph3P(CH2)3PPh3][PdBr4] and [Ph3P(CH2)3PPh3][Pd2Br6]·DMF were synthesized by the reaction of dihydrogentetrabromopalladic acid with trimethylenebis(triphenylphosphonium) dibromide in water with subsequent recrystallization from N,N-dimethylformamide. The recrystallization of the first of them from dimethyl sulfoxide leads to the formation of the complex [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2. Structure of the complexes was investigated by the X-ray diffraction (XRD) analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ab88635b657629b65b75b99ff4f80c88 https://doi.org/10.1134/s1070363217010194 Zobrazit plný text záznamu Plný text ve formátu PDF