Amino acid/zwitterion equilibria II: vibrational and NMR studies of substituted thiazolidine-4-carboxylic acids

Autor: H. E. Howard-Lock, Colin J. L. Lock, M. L. Martins
Rok vydání: 1991
Předmět:
Zdroj: Canadian Journal of Chemistry. 69:1721-1727
ISSN: 1480-3291
0008-4042
DOI: 10.1139/v91-252
Popis: Infrared and Raman spectra (4000–100 cm) of solid samples of seven different 2-phenyl-, N-benzoyl-, and 2-ethyl-2 methyl derivatives of L-cysteine and D-penicillamine have been observed and assigned. Proton and 13C nuclear magnetic resonance spectra for the compounds have also been measured. Amino acid/zwitterion equilibria are discussed with reference to pK values and the vibrational spectra. Key words: amino acid/zwitterion equilibria, thiazolidine carboxylic acids.
Databáze: OpenAIRE