Amino acid/zwitterion equilibria II: vibrational and NMR studies of substituted thiazolidine-4-carboxylic acids
Autor: | H. E. Howard-Lock, Colin J. L. Lock, M. L. Martins |
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Rok vydání: | 1991 |
Předmět: | |
Zdroj: | Canadian Journal of Chemistry. 69:1721-1727 |
ISSN: | 1480-3291 0008-4042 |
DOI: | 10.1139/v91-252 |
Popis: | Infrared and Raman spectra (4000–100 cm) of solid samples of seven different 2-phenyl-, N-benzoyl-, and 2-ethyl-2 methyl derivatives of L-cysteine and D-penicillamine have been observed and assigned. Proton and 13C nuclear magnetic resonance spectra for the compounds have also been measured. Amino acid/zwitterion equilibria are discussed with reference to pK values and the vibrational spectra. Key words: amino acid/zwitterion equilibria, thiazolidine carboxylic acids. |
Databáze: | OpenAIRE |
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