Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks

Autor: Megan C. Wasson, Haomiao Xie, Xingjie Wang, Joshua S. Duncan, Omar K. Farha
Rok vydání: 2022
Předmět:
Zdroj: CrystEngComm. 24:5135-5140
ISSN: 1466-8033
DOI: 10.1039/d2ce00650b
Popis: A rare example of phase transitions within Th-based MOFs is reported, relevant for nuclear energy and waste management. Further investigations into phase transitions in isostructural frameworks (Zr, Hf, Ce) provide a comparison of different hexanuclear clusters' stabilities.
Databáze: OpenAIRE