Correlation of polymethine dye basicity with parameters of the terminal heterocyclic nuclei

Autor:	Yu. M. Karpova, Lifshits Eh B, M. N. Ushomirskii
Rok vydání:	1989
Předmět:	End-group Terminal (electronics) Chemistry Stereochemistry Organic Chemistry Physical chemistry Molecule Linear correlation Polymethine dye Quantum
Zdroj:	Chemistry of Heterocyclic Compounds. 25:1071-1078
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00487314
Popis:	The basicity values of symmetrical polymethine dyes have been compared and correlated with a variety of parameters obtained both experimentally or derived by calculations, as well as with parameters obtained by quantum mechanical methods, characterizing the electron-donating abilities of the terminal heterocyclic residues. Linear correlations have been derived for the first time between the thermodynamic and spectral characteristics of these compounds and effective parameters of the heterocyclic nuclei. The basicity has been shown to be a universal characteristic not only of the end group but of the molecule as a whole.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ab15fe1751463447531327d79711de34 https://doi.org/10.1007/bf00487314 Zobrazit plný text záznamu Full text from SpringerLink