More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits
| Autor: | Konstiantyn V. Domasevitch, Christoph Janiak, Ishtvan Boldog, Bahareh Nateghi |
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| Rok vydání: | 2018 |
| Předmět: |
Zirconium
Structural organization Materials science Generalization chemistry.chemical_element Context (language use) 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Crystallography Octahedron chemistry Cluster (physics) General Materials Science Solvolysis 0210 nano-technology Porous medium |
| Zdroj: | CrystEngComm. 20:5132-5136 |
| ISSN: | 1466-8033 |
| Popis: | The largest known zirconium cluster with an idealized formula of [Zr26O18(OH)30(HCOO)38] was obtained via solvolysis of ZrOCl2 in DMF/HCOOH. The observed {Zr6} structural organization suggests generalization, with an outlook for even larger clusters promising in the context of organo–inorganic composites and porous materials including MOFs. |
| Databáze: | OpenAIRE |
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