The Direct Electrochemical Synthesis of Transition Metal Acetylacetonates

Autor:	J. J. Lagowski, S. R. Long
Rok vydání:	2007
Předmět:	Supporting electrolyte Acetylacetone Inorganic chemistry chemistry.chemical_element Manganese Electrochemistry Inorganic Chemistry Solvent chemistry.chemical_compound Transition metal chemistry Hexafluorophosphate Physical and Theoretical Chemistry Cobalt
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 37:813-815
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533170701748548
Popis:	Acetylacetonates were prepared electrochemically in good yield using the pure liquid ligand, acetylacetone, as the solvent, in which the supporting electrolyte, tetra‐n‐butyammonium hexafluorophosphate, was dissolved; the metal of interest served as the electrodes. The products were characterized by UV‐visible spectrometry (color) and mass spectrometry. Both a lower, M(AcAc)2, and a higher, M(AcAc)3, oxidate state were formed for the cobalt and manganese systems; the identity of the product(s) could be biased by a careful choice of the potential used for the synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ab0044a2182123c7311604a319f85781 https://doi.org/10.1080/15533170701748548 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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