Synthesis of oxazolidinofullerenes/thiazolidinofullerenes: novel reaction of [60]fullerene with isocyanates/isothiocyanates promoted by ferric perchlorate

Autor:	Li Liu, Fa-Bao Li, Ji-Long Shi, Xiao-Feng Zhang, Jun Wu, Liu Chen, Ye-Fei Zhu, Xiao-Xue Liang
Rok vydání:	2014
Předmět:	Reaction mechanism Fullerene Chemistry General Chemical Engineering Organic chemistry Product formation General Chemistry Dissolution Ferric perchlorate
Zdroj:	RSC Adv.. 4:48085-48094
ISSN:	2046-2069
DOI:	10.1039/c4ra10199e
Popis:	The facile one-step reaction of [60]fullerene with isocyanates/isothiocyanates in the presence of ferric perchlorate generates a series of oxazolidinofullerenes/thiazolidinofullerenes, which are difficult to prepare by common methods. The direct dissolution approach plays an important role in the efficient synthesis of oxazolidinofullerenes/thiazolidinofullerenes. A possible reaction mechanism for the product formation is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aafd9b6051b6520732593fdda7e250be https://doi.org/10.1039/c4ra10199e Zobrazit plný text záznamu