Formation of a Ruthenium μ‐Carbide Complex with Acetylene as the Carbon Source

Autor:	Sébastien Gauthier, Sasa Antonijevic, Rosario Scopelliti, Euro Solari, Kay Severin
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_compound Acetylene Phenylacetylene Chemistry Ligand Carbon source Polymer chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Photochemistry Carbide Ruthenium
Zdroj:	European Journal of Inorganic Chemistry. 2007:367-371
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.200600991
Popis:	Reactions of the dinuclear ruthenium complex [(p-cymene)Ru(mu-Cl)3RuCl(C2H4)(PCy3)] with phenylacetylene or tert-butylacetylene gave the vinylidene complexes [(p-cymene)Ru(mu-Cl)3RuCl(=C=CHR)(PCy3)] (R = tBu, Ph), which were characterized crystallographically. With acetylene, however, a tetranuclear -carbide complex was obtained as evidenced by single-crystal X-ray analysis as well as by solid-state NMR spectroscopy. Experiments with fully 13C-labelled acetylene showed that acetylene was the carbon source for the carbide ligand.
Databáze:	OpenAIRE
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