Synthesis of new photosensitive silicon-containing poly(salicylideneazomethynes)

Autor:	N. M. Geller, A. G. Ivanov, V. V. Shamanin, E. L. Aleksandrova, A. V. Gribanov
Rok vydání:	2008
Předmět:	Conductive polymer chemistry.chemical_classification Valence (chemistry) Polymers and Plastics Silicon Chemistry chemistry.chemical_element Quantum yield Polymer Photochemistry Photosensitivity Intramolecular force Polymer chemistry Materials Chemistry Ceramics and Composites Charge carrier
Zdroj:	Polymer Science Series B. 50:232-237
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090408090029
Popis:	Photosensitive silicon-containing poly(salicylideneazomethynes) have been synthesized. It has been shown that these polymers are characterized by the presence of intramolecular donor-acceptor interactions between valence shells of silicon and nitrogen atoms; as a result, polyconjugation appears according to the nonclassical mechanism. The photo-and electrophysical properties of the polymers have been examined. The introduction of an oxygen spacer into a polymer facilitates an increase in the photosensitivity and quantum yield of free charge carrier photogeneration, and it has almost no effect on the conductive behavior of the polymers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aac7345eeb6c9b6440c8c48d56cc6e46 https://doi.org/10.1134/s1560090408090029 Zobrazit plný text záznamu Full text from SpringerLink