Recherches dans la série des cyclitols XLII. Synthèses de cyclitolstout-cisdérivés du cyclopentane; préparation des cyclopentane-tétrol et - pentoltout-cis

Autor:	F. G. Cocu, Th. Posternak
Rok vydání:	1971
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Dimethyl sulfoxide Organic Chemistry Drug Discovery Halogen Physical and Theoretical Chemistry Sodium hydrogencarbonate Cyclopentane Biochemistry Catalysis
Zdroj:	Helvetica Chimica Acta. 54:1676-1687
ISSN:	0018-019X
DOI:	10.1002/hlca.19710540619
Popis:	All-cis cyclitols derived from cyclopentane have been prepared in two ways: (i) by LiAlH4 reduction of all-cis epoxypolyos; (ii) by dimethyl sulfoxide treatment, in the presence of sodium hydrogencarbonate, of brominated derivatives containing a neighbouring benzoyloxy group; under these conditions, the halogen is replaced by a cis-oriented hydroxyl group. Thus all-cis cyclopentane-tetrol and -pentol have been prepared; their configuration has been confirmed by NMR. spectroscopy.
Databáze:	OpenAIRE
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