The synthesis and comparative characterization of three novel electroactive iminoboronates containing ferrocene

Autor:	Karel Lacina, Monika Skrutková Langmajerová, Martin Konhefr, Ctibor Mazal, Petr Skládal, Zdeněk Glatz
Rok vydání:	2017
Předmět:	010405 organic chemistry Imine General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Ferrocene chemistry Polymer chemistry Structural isomer Moiety Organic chemistry Lewis acids and bases Phenylboronic acid Cyclic voltammetry Boronic acid
Zdroj:	Monatshefte für Chemie - Chemical Monthly. 148:1953-1958
ISSN:	1434-4475 0026-9247
DOI:	10.1007/s00706-017-2028-3
Popis:	Along our way towards the advanced saccharide-sensitive probes, three novel electroactive iminoboronate regioisomers of [(ferrocenylimino)methyl]phenylboronic acid have been synthesized. The ortho, meta, and para regioisomers were characterized structurally by NMR, MS, FT-IR, UV/Vis and their electrochemical behavior in aqueous solution was studied using cyclic voltammetry. The obtained results confirmed different behavior of the ortho isomer due to an interaction of boronic acid moiety with the proximate imine group of the iminoferrocenyl residue.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aaaadfc922a4d39b98a5016ccc96ec9b https://doi.org/10.1007/s00706-017-2028-3 Zobrazit plný text záznamu Full text from SpringerLink