Lignosulfonate for improving electrochemical performance of chitin derived carbon materials as a superior anode for lithium-ion batteries
| Autor: | Huanhuan Yin, Qiwen Jiang, Yi Jing, Yeyan Ni, Ruoshi Gao, Yaqi Wang, Jian Zhang, Jie Wang |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Dopant Mechanical Engineering Metals and Alloys chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Energy storage 0104 chemical sciences Anode Chemical engineering chemistry Mechanics of Materials Specific surface area Materials Chemistry Lithium 0210 nano-technology Carbon Pyrolysis |
| Zdroj: | Journal of Alloys and Compounds. 885:160973 |
| ISSN: | 0925-8388 |
| DOI: | 10.1016/j.jallcom.2021.160973 |
| Popis: | Lignosulfonate, a by-product spent sulfite pulping liquor from the paper and pulping industry, was a suitable natural sulfur dopant for improving electrochemical performance of chitin derived carbon materials. Herein, a cost-effective method of possible large-scale production was reported to fabricate heteroatoms-doped porous carbon (CLs) as advanced electrode materials for lithium-ion batteries applications. After a simple pyrolysis process of chitin mixed with lignosulfonate, generated CLsequipped with abundant defect structures. Remarkably, although portion of lignosulfonate (1/3 of chitin) was introduced, the specific surface area (SSA) of CLs enhanced to 411.64 m2g−1 (CL800). In addition, its capacitive characteristic improved, effectively, delivering high a reversible specific capacity of up to 644.5 mA h g−1 at current density of 50 mA g−1. After 300 cycles at the current density of 100 mA g−1, it still remained a specific capacity of 350.7 mA g−1. Such anode material presented excellent electrochemical performance, good rate capability and cycling stability, attributed to containing abundant N and S elements, providing a green avenue for converting biomass waste to high electrochemical performance heteroatoms-doped carbon materials, having promising application in the energy storage field. |
| Databáze: | OpenAIRE |
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